Photoredox-Catalyzed Functionalization of Amines : Remote Directed C-H Activation, Selective N-Demethylation and Oxime Isomerization /
In Chapter 3, utilizing photoinduced ligand dissociation of nickel complex, we developed selective N-demethylation of trialkylamines, where C(sp2) radicals generated from aryl bromides are employed as HAT reagents. The site selectivity of N-demethylation was further improved by steric manipulation o...
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| Format: | Thesis Book |
| Language: | English |
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[New York, N.Y.?] :
[publisher not identified],
2023
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Internet
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