Tandem organic reactions /
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York :
Wiley,
1992
New York : [1992], ©1992 New York : c1992 New York : [1992] |
| Subjects: |
Table of Contents:
- 1 Introduction
- 2. Aldol Condensation. 2.1. Michael - Aldol Tandems. 2.2. Claisen - Aldol and Multiple Aldol Condensations. 2.3. Retro-Aldol - Aldol Tandems. 2.4. Mannich - Aldol Tandems. 2.5. Rearrangement - Aldol Tandems. 2.6. Aldol-Type Reactions in Tandem with Other Processes
- 3. Michael Reactions. 3.1. Michael Reactions Initiated by Other Reactions. 3.2. Double Michael Reactions. 3.3. Reflexive Michael Reactions
- 4. Tandem Vicinal Difunctionalization of Alkenes and Alkynes. 4.1. Michael Reaction/Electrophilation. 4.2. vic-Difunctionalization of Temporarily Activated Alkenes. 4.3. Pauson - Khand Cyclization and Dotz Reaction. 4.4. Intramolecular Metallo - Ene Reactions and Related CC Bond Formation Processes. 4.5. Cationic Polyene Cyclizations. 4.6. Miscellaneous vic-Dialkylations
- 5. Dieckmann and Claisen Cyclizations. 5.1. Michael - Dieckmann and Michael - Claisen Reaction Tandems. 5.2. Alkylation - Dieckmann and Related Tandem Reactions. 5.3. Tandem Reactions Terminated by Claisen Condensation
- 6. Mannich Reaction. 6.1. Schiff Condensation - Mannich Cyclization. 6.2. Manifold Mannich Reactions. 6.3. Alkylation or Acylation - Mannich Cyclization. 6.4. Retro - Mannich Fragmentation - Mannich Cyclization. 6.5. Mannich Cyclization Following Oxidation or Reduction. 6.6. Cationic Aza-Cope Rearrangement - Mannich Cyclization and Others
- 7. Diels - Alder Reactions. 7.1. Elimination/Diels - Alder Reaction Tandems. 7.2. Retro-Diels - Alder/Diels - Alder Reactions. 7.3. Electrocyclic/Diels - Alder Reactions. 7.4. Diels - Alder Reactions Preceded by Other Pericyclic Reactions. 7.5. Acylation/Diels - Alder Reaction Tandems. 7.6. Oxidation or Reduction Initiated Diels - Alder Reactions. 7.7. Intramolecularization. 7.8. Assorted Triggers for the Diels - Alder Reaction
- 8. Other Cycloadditions. 8.1. [2 + 2]-Cycloadditions. 8.2. [2 + 2 + 2]-Cycloadditions. 8.3. Formation of Five-Membered Rings by Concerted Cycloadditions. 8.4. Higher-Order Cycloadditions. 8.5. 1,3-Dipolar Cycloadditions
- 9. Retro-Diels - Alder and Cheletropic Reactions. 9.1. Diels - Alder/Retro-Diels - Alder Reaction Tandems. 9.2. Retro-Diels - Alder Reactions Following Other Processes. 9.3. Some Other Cheletropic Reactions
- 10. Electrocyclic Reactions. 10.1. Electrocyclic Reaction Cascades. 10.2. Cycloaddition or Cycloreversion/Electrocyclic Reaction Tandems. 10.3. Rearrangement - Electrocyclic Reaction Tandems. 10.4. Electrocyclic Reactions Induced by Enolization, Elimination, Condensation, or Other Processes
- 11. Ene, Retro-Ene, and Some Other Thermal Reactions. 11.1. Ene Reactions. 11.2. Retro-Ene Reactions. 11.3. Vinylcyclopropane-to-Cyclopentene Rearrangements
- 12. Sigmatropic Rearrangements. 12.1. [1, n]-Sigmatropic Rearrangements. 12.2. [3.3]-Sigmatropic Rearrangements
- 13. Rearrangements and Fragmentations. 13.1. Rearrangements. 13.2. Fragmentation Reactions
- 14. Free Radical Reactions. 14.1. Vicinal CC Bond Formations. 14.2. 1,3-Diyl Cycloadditions. 14.3. Addition - Fragmentation Tandems. 14.4. Reactions of Carbinyl Radicals Adjacent to a Small Ring. 14.5. Miscellaneous Radical Reaction Tandems
- 15. Miscellaneous Tandem Reactions. 15.1. Wittig and Related Reactions. 15.2. Electrophilations. 15.3. Eliminations and Ring Openings. 15.4. Stitching of Alkenes and Alkynes. 15.5. Tandem Reactions Involving Oxidoreductions.
- Machine derived contents note: Aldol Condensation.
- Michael Reactions.
- Tandem Vicinal Difunctionalization of Alkenes and Alkynes.
- Dieckmann and Claisen Cyclizations.
- Mannich Reaction.
- Diels-Alder Reactions.
- Other Cycloadditions.
- Retro-Diels-Alder and Cheletropic Reactions.
- Electrocyclic Reactions.
- Ene, Retro-Ene, and Some Other Thermal Reactions.
- Sigmatropic Rearrangements.
- Rearrangements and Fragmentations.
- Free Radical Reactions.
- Miscellaneous Tandem Reactions.
- References.
- Index